The Solvent Extraction of Tin (IV)-Pyrocatechol Violet Chelate with Tridodecylethylammonium Bromide
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Naked-eye detection of fluoride using Zr(IV)-EDTA complex and pyrocatechol violet.
A method for the visual detection of fluoride is presented using an aqueous solution of Pyrocatechol Violet (PV), which changes its color from yellow to blue by the formation of a ternary complex with Zr(H2O)2EDTA; also, the blue color of PV-Zr-EDTA readily shifts to orange red upon the addition of a moderate concentration of fluoride. The mechanism has been interpreted by a ligand-exchange rea...
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A simple, rapid and sensitive method has been developed for determination of traces of tellurium (IV) (7.0-120.0 ng/ml) based on it’s catalytic effect on the reduction reaction of lauth’s violet by sulfide ion at pH 4.2. The reaction is monitored spectrophotometrically by measuring the decrease in absorbance of lauth’s viole at 600 nm by the fixed time method. The detection limit is 5.0 ng/ml a...
متن کاملCrystal structure of a one-dimensional coordination polymer of tin(IV) bromide with 1,4-dithiane
The title compound, [SnBr4(C4H8S2)] {systematic name: catena-poly[[tetrabromidotin(IV)]-μ-1,4-dithiane-κ(2) S:S']}, represents the first 1,4-di-thiane complex with tin as coordination centre. The asymmetric unit consist of half a formula unit with the tin(IV) atom at the centre of symmetry at 0,0,1/2 (Wyckoff symbol b) and a centrosymmetric 1,4-di-thiane mol-ecule with the centre of symmetry in...
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BACKGROUND For clinicians, it is important to rely on accurate laboratory results for patient care and optimal use of health care resources. We sought to explore our observations that urine protein:creatinine ratios (PrCr) ≥30 mg/mmol are seen not infrequently associated with normal pregnancy outcome. METHODS Urine samples were collected prospectively from 160 pregnant women attending high-ri...
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Ion pair dispersive liquid- liquid microextraction (IP-DLLME) method combined with flame atomic absorption spectrometry was proposed for the determination of trace amounts of copper(II). By using pyrocatechol violet as chelating agent and cetyltrimethyl ammonium bromide as an ion pairing agent, the trace amount of copper(II) was extracted in chloroform. The factors influencing the formation cop...
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ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1974
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1974.1658